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Green process to recover magnesium chloride from residue solution of potassium chloride production plant

WANG Lin, HE Yunliang, WANG Yanfei, BAO Ying, WANG Jingkang

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 4,   Pages 385-389 doi: 10.1007/s11705-008-0079-z

Abstract: The green process to recover magnesium chloride from the residue solution of a potassium chloride productionThe residue solution contains magnesium chloride above 25 wt-%, potassium chloride and sodium chlorideThe crystallized impurity carnallite obtained from the first step is recycled to the potassium chlorideplant to recover the potassium salt.The produced magnesium chloride is up to industrial criteria.

Keywords： industrial production     chemical industrial     produced magnesium     chloride production     impurity carnallite    

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Influences of additives on the crystal habit of potassium chloride

Xiaofu GUO, Junsheng YUAN, Zhiyong JI, Min SU,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 1,   Pages 78-81 doi: 10.1007/s11705-009-0300-8

Abstract: of constant control speed cooling crystallization, the influences of four additives, including lead chloride, cadmium chloride, sodium salicylate, and quaternary ammonium salt, on the crystal habit of KCl were

Keywords： cadmium chloride     salicylate     presence     crystallization     diffractometry analysis    

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Chemical deactivation of V

Xiaodong WU, Wenchao YU, Zhichun SI, Duan WENG

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3,   Pages 420-427 doi: 10.1007/s11783-013-0489-0

Abstract: The addition of ammonia chloride enlarges the pore size of the titania support, and promotes the formationMore importantly, potassium can reduce the Br?more severe deactivation of the KCl-treated catalyst can be mainly ascribed to the higher amount of potassium

Keywords： V2O5-WO3/TiO2     potassium chloride     poisoning     reducibility     acid    

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Effect of potassium carbonate on catalytic synthesis of calcium carbide at moderate temperature

Dejun SHI, Ke QIAO, Zifeng YAN

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 3,   Pages 372-375 doi: 10.1007/s11705-010-0570-1

Abstract: The effect of potassium carbonate as additive on the composition and morphology of the product was investigatedAddition of potassium carbonate increased the yield of calcium carbide.The sample in the presence of potassium carbonate generated acetylene gas of 168.3 L/kg, which was 10%higher than that in the absence of potassium carbonate.This result confirmed the catalytic effect of potassium carbonate on the synthesis of calcium carbide

Keywords： calcium carbide     synthesis     catalysis    

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Insight of chemical environmental risk and its management from the vinyl chloride accident

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 4, doi: 10.1007/s11783-023-1652-x

Abstract: The combustion of vinyl chloride (VC) after the train derailment accident in Ohio, USA in February, 2023

Keywords： Vinyl chloride     Combustion     Chemical safety management     Environmental risk     Emerging contaminants    

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Evaluating effect of chloride attack and concrete cover on the probability of corrosion

Sanjeev Kumar VERMA, Sudhir Singh BHADAURIA, Saleem AKHTAR

Frontiers of Structural and Civil Engineering 2013, Volume 7, Issue 4,   Pages 379-390 doi: 10.1007/s11709-013-0223-9

Abstract: recently performed chlorination studies, and from results of a field survey evaluates the effect of chloridecontent on the probability of corrosion and the influence of concrete compressive strength on the chloridecontent and penetration, also evaluates the effect of concrete cover over the chloride content of the

Keywords： concrete     chloride     reinforcement     corrosion     deterioration     cover    

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Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts

Jinli ZHANG, Nan LIU, Wei LI, Bin DAI

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 4,   Pages 514-520 doi: 10.1007/s11705-011-1114-z

Abstract: Polyvinyl chloride (PVC) has become the third most used plastic after polyethylene and polypropylenePolyvinyl chloride is produced by polymerization of the vinyl chloride monomer (VCM), which is manufacturedHowever, the industrial production of VCM utilizes a mercuric chloride catalyst to promote the reactionof acetylene and hydrogen chloride.During the hydrochlorination, the highly toxic mercuric chloride tends to sublime, resulting in the deactivation

Keywords： polyvinyl chloride     vinyl chloride monomer     acetylene hydrochlorination     non-mercury catalysts     green chemical    

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Chloride binding and time-dependent surface chloride content models for fly ash concrete

S. MUTHULINGAM,B. N. RAO

Frontiers of Structural and Civil Engineering 2016, Volume 10, Issue 1,   Pages 112-120 doi: 10.1007/s11709-015-0322-x

Abstract: embedded rebars is a classical deterioration mechanism of reinforced concrete structures exposed to chlorideChloride ingress into concrete, essential for inducing rebar corrosion, is a complex interaction betweenchloride content under tidal exposure condition; and 2) chloride binding.First, inconsistencies in surface chloride content and chloride binding models reported in literatureSecondly, to avoid such inconsistencies, surface chloride content and chloride binding models for fly

Keywords： binding isotherms     chloride ingress     concrete     fly ash     surface chloride content    

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Experimental study on high-efficiency polishing for potassium dihydrogen phosphate (KDP) crystal by using

Ziyuan LIU, Hang GAO, Dongming GUO

Frontiers of Mechanical Engineering 2020, Volume 15, Issue 2,   Pages 294-302 doi: 10.1007/s11465-019-0576-4

Abstract: surface contamination and solve the inefficiency of previous water-dissolution polishing techniques for potassium

Keywords： potassium dihydrogen phosphate (KDP) crystal     controllable deliquescence     two-phase air–water fluid     high-efficiency    

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On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

Frontiers in Energy 2010, Volume 4, Issue 2,   Pages 181-184 doi: 10.1007/s11708-009-0065-2

Abstract: A calcium chloride solution with a different extender, which is made up of either pure calcium chloride, calcium chloride with expanded graphite, or calcium chloride with activated carbon, acts differentlyThe mass ratio between calcium chloride with expanded graphite or activated carbon is almost 4∶, calcium chloride with expanded graphite, and calcium chloride with activated carbon, the strongest, the weakest oxidation creation happened in the solution of calcium chloride with activated carbon,

Keywords： stainless steel     corrosion     calcium chloride     expanded graphite     activated carbon     oxidation creation     pitting    

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A space power system of free piston Stirling generator based on potassium heat pipe

Mingqiang LIN, Jian MOU, Chunyun CHI, Guotong HONG, Panhe GE, Gu HU

Frontiers in Energy 2020, Volume 14, Issue 1,   Pages 1-10 doi: 10.1007/s11708-019-0655-6

Abstract: The power system of a free piston Stirling generator (FPSG) based on potassium heat pipes has been developedBesides, the power system integrated with four FPSGs and potassium heat pipes was performed and the single

Keywords： free piston Stirling generator (FPSG)     potassium heat pipe     power system     energy conversion    

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Effect of adding a smart potassium ion-responsive copolymer into polysulfone support membrane on the

Meibo He, Zhuang Liu, Tong Li, Chen Chen, Baicang Liu, John C. Crittenden

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 2,   Pages 400-414 doi: 10.1007/s11705-018-1757-0

Abstract: Thin-film composite (TFC) nanofiltration (NF) membranes were fabricated via the interfacial polymerization of piperazine (PIP) and 1,3,5-benzenetricarbonyl trichloride on polysulfone (PSf) support membranes blended with K -responsive poly( -isopropylacryamide-co-acryloylamidobenzo-15-crown-5) (P(NIPAM-co-AAB C )). Membranes were characterized by attenuated total reflection Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, atomic force microscope, scanning electron microscope, contact angle, and filtration tests. The results showed that: (1) Under K -free conditions, the blended P(NIPAM-co-AAB C )/PSf supports had porous and hydrophilic surfaces, thereby producing NF membranes with smooth surfaces and low MgSO rejections; (2) With K in the PIP solution, the surface roughness and water permeability of the resultant NF membrane were increased due to the K -induced transition of low-content P(NIPAM-co-AAB C ) from hydrophilic to hydrophobic; (3) After a curing treatment at 95 °C, the improved NF membrane achieved an even higher pure water permeability of 10.97 L·m ·h ·bar under 200 psi. Overall, this study provides a novel method to improve the performance of NF membranes and helps understand the influence of supports on TFC membranes.

Keywords： nanofiltration     interfacial polymerization     support membrane     potassium ion-responsive     thin-film composite    

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Coupled diffusion of chloride and other ions in saturated concrete

Nattapong DAMRONGWIRIYANUPAP, Linyuan LI, Yunping XI

Frontiers of Structural and Civil Engineering 2011, Volume 5, Issue 3,   Pages 267-277 doi: 10.1007/s11709-011-0112-z

Abstract: Corrosion of reinforcing steel due to chloride ions is one of the severe deterioration problems in long-termThe diffusion of chloride ions is associated and strongly affected by other ions in the pore solutionIn this paper, chloride penetration into concrete structures was mathematically characterized by theNernst-Planck equation which considered not only diffusion mechanism of the chloride ions but also ionicThe material models of chloride binding capacity and chloride diffusion coefficient were incorporated

Keywords： diffusion     chloride     concrete     Nernst-Planck equation     durability    

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Long-term durability of onshore coated concrete —chloride ion and carbonation effects

Seyedhamed SADATI,Mehdi K. MORADLLO,Mohammad SHEKARCHI

Frontiers of Structural and Civil Engineering 2016, Volume 10, Issue 2,   Pages 150-161 doi: 10.1007/s11709-016-0341-2

Abstract: Surface chloride ion build-up and variation in chloride ion diffusion were monitored with respect to

Keywords： carbonation     chloride ion     corrosion     service life     surface coating    

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Impacts of climate change on optimal mixture design of blended concrete considering carbonation and chloride

Xiao-Yong WANG

Frontiers of Structural and Civil Engineering 2020, Volume 14, Issue 2,   Pages 473-486 doi: 10.1007/s11709-020-0608-5

Abstract: Second, strength, slump, carbonation, and chloride ingress models are used to evaluate concrete propertiesThe effect of different climate change scenarios on carbonation and chloride ingress is considered.

Keywords： ternary blended concrete     climate change     optimal mixture design     carbonation     chloride ingress    

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Title Author Date Type Operation

Green process to recover magnesium chloride from residue solution of potassium chloride production plant

WANG Lin, HE Yunliang, WANG Yanfei, BAO Ying, WANG Jingkang

Journal Article

Influences of additives on the crystal habit of potassium chloride

Xiaofu GUO, Junsheng YUAN, Zhiyong JI, Min SU,

Journal Article

Chemical deactivation of V

Xiaodong WU, Wenchao YU, Zhichun SI, Duan WENG

Journal Article

Effect of potassium carbonate on catalytic synthesis of calcium carbide at moderate temperature

Dejun SHI, Ke QIAO, Zifeng YAN

Journal Article

Insight of chemical environmental risk and its management from the vinyl chloride accident

Journal Article

Evaluating effect of chloride attack and concrete cover on the probability of corrosion

Sanjeev Kumar VERMA, Sudhir Singh BHADAURIA, Saleem AKHTAR

Journal Article

Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts

Jinli ZHANG, Nan LIU, Wei LI, Bin DAI

Journal Article

Chloride binding and time-dependent surface chloride content models for fly ash concrete

S. MUTHULINGAM,B. N. RAO

Journal Article

Experimental study on high-efficiency polishing for potassium dihydrogen phosphate (KDP) crystal by using

Ziyuan LIU, Hang GAO, Dongming GUO

Journal Article

On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

Journal Article

A space power system of free piston Stirling generator based on potassium heat pipe

Mingqiang LIN, Jian MOU, Chunyun CHI, Guotong HONG, Panhe GE, Gu HU

Journal Article

Effect of adding a smart potassium ion-responsive copolymer into polysulfone support membrane on the

Meibo He, Zhuang Liu, Tong Li, Chen Chen, Baicang Liu, John C. Crittenden

Journal Article

Coupled diffusion of chloride and other ions in saturated concrete

Nattapong DAMRONGWIRIYANUPAP, Linyuan LI, Yunping XI

Journal Article

Long-term durability of onshore coated concrete —chloride ion and carbonation effects

Seyedhamed SADATI,Mehdi K. MORADLLO,Mohammad SHEKARCHI

Journal Article

Impacts of climate change on optimal mixture design of blended concrete considering carbonation and chloride

Xiao-Yong WANG

Journal Article